ʳƷ°ü×°ÐÐÒµÖо۰±õ¥±íÃæ»îÐÔ¼ÁµÄÓ¦Óã¬È·±£Ê³Æ·°²È«
¾Û°±õ¥±íÃæ»îÐÔ¼ÁÔÚʳƷ°ü×°ÖеÄÓ¦ÓãºÈ·±£Ê³Æ·°²È«µÄÄ»ºóÓ¢ÐÛ
Ò»¡¢ÒýÑÔ
ÔÚÏÖ´úÉç»á£¬Ê³Æ·°ü×°ÔçÒѲ»½ö½öÊDZ£»¤Ê³ÎïÄÇô¼òµ¥¡£ËüÏñһλÖҳϵÄÎÀÊ¿£¬²»½öÒªµÖÓùÍâ½ç»·¾³µÄÇÖÏ®£¬»¹Òª±£Ö¤Ê³Æ·µÄ°²È«ÓëÐÂÏÊ¡£¶øÔÚÕâÆäÖУ¬¾Û°±õ¥±íÃæ»îÐÔ¼Á×÷ΪһÖÖÉñÆæµÄ¡°Ä§·¨Ò©Ë®¡±£¬ÕýÔÚÇÄÈ»¸Ä±ä×ÅʳƷ°ü×°ÐÐÒµµÄÃæÃ²¡£ËüÃǾÍÏñÊÇһȺÒþÃØµÄ¹¤½³£¬ÔÚ²»ÎªÈËÖªµÄµØ·½Ê©Õ¹×Å×Ô¼ºµÄ¼¼ÒÕ£¬ÈÃʳƷ°ü×°¸ü¼Ó°²È«¡¢ÄÍÓúͻ·±£¡£
1.1 ʳƷ°ü×°µÄÖØÒªÐÔ
ʳƷ°ü×°ÊÇÁ¬½ÓʳƷÉú²úºÍÏû·ÑÕßÖ®¼äµÄÇÅÁº¡£ÏëÏóһϣ¬Èç¹ûûÓкÏÊʵİü×°£¬Ê³Îï»áѸËÙ±äÖÊ£¬ÓªÑø³É·ÖÁ÷ʧ£¬ÉõÖÁ¿ÉÄÜÒý·¢½¡¿µÎÊÌâ¡£Òò´Ë£¬Ñ¡ÔñºÏÊʵİü×°²ÄÁÏÖÁ¹ØÖØÒª¡£È»¶ø£¬´«Í³µÄ°ü×°²ÄÁÏÍùÍù´æÔÚһЩȱÏÝ£¬ÀýÈçÍ¸ÆøÐԲÒׯÆËðµÈ¡£Õâ¾ÍÐèÒªÒýÈëÒ»ÖÖÌØÊâµÄÌí¼Ó¼Á¡ª¡ª¾Û°±õ¥±íÃæ»îÐÔ¼ÁÀ´ÌáÉý°ü×°ÐÔÄÜ¡£
1.2 ¾Û°±õ¥±íÃæ»îÐÔ¼ÁµÄ½ÇÉ«
¾Û°±õ¥±íÃæ»îÐÔ¼ÁÊÇÒ»Öֶ๦ÄÜ»¯ºÏÎËü¿ÉÒÔ¸ÄÉÆ²ÄÁϵÄÎïÀíÌØÐÔ£¬ÔöÇ¿ÈáÈÍÐÔ£¬¼õÉÙĦ²Á£¬²¢Ìá¸ß·ÀË®ÐÔºÍÄÍ»¯Ñ§ÐÔ¡£¶ÔÓÚʳƷ°ü×°À´Ëµ£¬ÕâÐ©ÌØÐÔÒâζןüºÃµÄÃÜ·âЧ¹û¡¢¸ü³¤µÄ±£ÖÊÆÚÒÔ¼°¸ü¸ßµÄ°²È«ÐÔ¡£¿ÉÒÔ˵£¬¾Û°±õ¥±íÃæ»îÐÔ¼ÁÊÇʳƷ°ü×°ÁìÓò²»¿É»òȱµÄ¡°ÃØÃÜÎäÆ÷¡±¡£
¶þ¡¢¾Û°±õ¥±íÃæ»îÐÔ¼ÁµÄ»ù±¾ÔÀí
ÒªÀí½â¾Û°±õ¥±íÃæ»îÐÔ¼ÁÈçºÎ·¢»Ó×÷Óã¬ÎÒÃÇÊ×ÏÈÐèÒªÁ˽âËüµÄ»ù±¾½á¹¹ºÍ×÷ÓûúÖÆ¡£¼òµ¥À´Ëµ£¬¾Û°±õ¥±íÃæ»îÐÔ¼ÁÊÇÓÉÇ×Ë®»ùÍźÍÊèË®»ùÍÅ×é³ÉµÄÁ½Ç×ÐÔ·Ö×Ó¡£ÕâÖÖ¶ÀÌØµÄË«ÃæÐÔ¸ñʹËüÄܹ»ÔÚ²»Í¬µÄ½çÃæÖ®¼ä¼ÜÆðÇÅÁº£¬´Ó¶øÊµÏÖһϵÁÐÁîÈ˾ªÌ¾µÄ¹¦ÄÜ¡£
2.1 »¯Ñ§½á¹¹
¾Û°±õ¥±íÃæ»îÐÔ¼ÁµÄ»¯Ñ§½á¹¹Ö÷ÒªÓÉÒÔϼ¸¸ö²¿·Ö×é³É£º
- Ó²¶Î£ºÌṩ¸ÕÐԺͻúеǿ¶È¡£
- Èí¶Î£º¸³Ó赯ÐÔ¼°ÈáÈÍÐÔ¡£
- ¹¦ÄÜÐÔ»ùÍÅ£ºÈçôÇ»ù¡¢°±»ùµÈ£¬ÓÃÓÚµ÷½Ú·´Ó¦»îÐÔ¡£
ͨ¹ýµ÷ÕûÕâЩ×é·ÖµÄ±ÈÀýºÍÖÖÀ࣬¿ÉÒÔ¶¨ÖƳöÂú×ãÌØ¶¨ÐèÇóµÄ±íÃæ»îÐÔ¼Á¡£ÀýÈ磬ijЩ²úÆ·¿ÉÄܸü×¢ÖØÈáÈÍÐÔ£¬¶øÁíһЩÔòÇ¿µ÷ÄÍÄ¥ÐÔ»ò¿¹×ÏÍâÏßÄÜÁ¦¡£
| ×é·Ö | ¹¦ÄÜÃèÊö | Ó¦Óó¡¾° |
|---|---|---|
| Ó²¶Î | Ìṩ¸ÕÐÔ£¬ÔöÇ¿ÄÍÈÈÐÔ | ¸ßλ·¾³ÏÂʹÓà |
| Èí¶Î | Ôö¼ÓÈáÈÍÐԺͻص¯ÐÔ | ÈáÐÔ°ü×°²ÄÁÏ |
| ¹¦ÄÜÐÔ»ùÍÅ | ¸ÄÉÆ¸½×ÅÁ¦¡¢·ÖÉ¢ÐÔºÍÎȶ¨ÐÔ | ¸´ºÏ²ÄÁÏÍ¿²ã |
2.2 ×÷ÓûúÖÆ
µ±¾Û°±õ¥±íÃæ»îÐÔ¼Á±»Ìí¼Óµ½Ê³Æ·°ü×°²ÄÁÏÖÐʱ£¬Ëü»áÇ¨ÒÆµ½²ÄÁϱíÃæ²¢ÐγÉÒ»²ã¾ùÔȵı¡Ä¤¡£Õâ²ã±¡Ä¤¾ßÓÐÒÔϼ¸Öֹؼü×÷Óãº
- ½µµÍ±íÃæÕÅÁ¦£ºÊ¹µÃÒºÌå¸üÈÝÒׯÌÕ¹£¬´Ó¶ø¸ÄÉÆÓ¡Ë¢Ð§¹ûºÍÍ¿²ã¸½×ÅÁ¦¡£
- ÔöÇ¿ÆÁÕÏÐÔÄÜ£º×èÖ¹ÑõÆø¡¢Ë®·ÖºÍÆäËûÓк¦ÎïÖÊÉøÍ¸µ½Ê³Æ·ÄÚ²¿¡£
- ¸ÄÉÆ¼Ó¹¤ÐÔÄÜ£º¼õÉÙÉ豸ĥËð£¬ÑÓ³¤Éú²úÏßÊÙÃü¡£
Èý¡¢¾Û°±õ¥±íÃæ»îÐÔ¼ÁÔÚʳƷ°ü×°ÖеľßÌåÓ¦ÓÃ
Ëæ×ſƼ¼µÄ½ø²½£¬¾Û°±õ¥±íÃæ»îÐÔ¼ÁÒѾ¹ã·ºÓ¦ÓÃÓÚ¸÷ÖÖÀàÐ͵ÄʳƷ°ü×°ÖС£´ÓÈÕ³£Éú»îÖг£¼ûµÄËÜÁÏ´üµ½¸ß¶ËµÄÕæ¿Õ±£ÏʺУ¬¶¼¿ÉÒÔ¿´µ½ËüµÄÉíÓ°¡£ÏÂÃæÎÒÃÇÏêϸ̽ÌÖ¼¸ÖÖµäÐ͵ÄÓ¦Óð¸Àý¡£
3.1 ÔÚËÜÁϰü×°ÖеÄÓ¦ÓÃ
ËÜÁÏÊÇʳƷ°ü×°Öг£ÓõIJÄÁÏÖ®Ò»£¬µ«ÆÕͨËÜÁÏÈÝÒ׳öÏÖÀÏ»¯¡¢¿ªÁѵÈÎÊÌâ¡£¾Û°±õ¥±íÃæ»îÐÔ¼ÁÄܹ»ÓÐЧ½â¾öÕâЩÎÊÌ⣬ͬʱÌáÉýÆä¹âѧ͸Ã÷¶ÈºÍ×è¸ôÐÔÄÜ¡£
3.1.1 Ìá¸ß×è¸ôÐÔÄÜ
Ñо¿±íÃ÷£¬º¬Óо۰±õ¥±íÃæ»îÐÔ¼ÁµÄËÜÁÏĤ¶ÔÑõÆøºÍ¶þÑõ»¯Ì¼µÄ͸¹ýÂÊÏÔÖø½µµÍ£¨²Î¿¼ÎÄÏ×[1]£©¡£ÕâÒâζ×ÅʳƷ¿ÉÒÔÔÚ¸ü³¤Ê±¼äÄÚ±£³ÖÐÂÏÊ״̬£¬±ÜÃâÒòÑõ»¯¶øµ¼Öµķçζ±ä»¯»òÓªÑø¼ÛÖµËðʧ¡£
| ²ÎÊý | ÆÕͨËÜÁÏĤ | º¬¾Û°±õ¥±íÃæ»îÐÔ¼ÁËÜÁÏĤ |
|---|---|---|
| ÑõÆøÍ¸¹ýÂÊ (cm?/m?¡¤day) | 50 | 10 |
| Ë®ÕôÆøÍ¸¹ýÂÊ (g/m?¡¤day) | 2.5 | 0.8 |
3.1.2 ÔöÇ¿¿¹ÎÛȾÄÜÁ¦
ÓÉÓÚ¾Û°±õ¥±íÃæ»îÐÔ¼ÁÐγɵı£»¤²ã¾ßÓнÏÇ¿µÄÊèË®ÐÔºÍÊèÓÍÐÔ£¬Òò´Ë¿ÉÒÔÓÐЧ·ÀÖ¹ÓÍÖ¬ºÍÎÛ¹¸¸½×ÅÔÚ°ü×°±íÃæ¡£Õâ¶ÔÓÚ¿ì²ÍʳƷÓÈÆäÖØÒª£¬ÒòΪËüÃÇͨ³£ÐèÒª¾¹ý¶à´ÎÔËÊäºÍ´¢´æ¡£
3.2 ÔÚÖ½ÖÆÆ·°ü×°ÖеÄÓ¦ÓÃ
ËäÈ»ËÜÁÏÒòÆäÓÅÒìµÄÐÔÄÜÕ¼¾ÝÁËÖ÷µ¼µØÎ»£¬µ«ÔÚ»·±£ÒâʶÈÕÒæÔöÇ¿µÄ½ñÌì£¬Ö½ÖÆÆ·ÖØÐ»ñµÃÁ˹Ø×¢¡£È»¶ø£¬´¿Ö½°ü×°ÍùÍùÎÞ·¨Âú×ãÏÖ´úʳƷ¹¤ÒµµÄÐèÇó¡£´Ëʱ£¬¾Û°±õ¥±íÃæ»îÐÔ¼Á±ã³ÉΪÁËÒ»ÖÖÀíÏëµÄ½â¾ö·½°¸¡£
3.2.1 ÌáÉý·ÀË®ÐÔÄÜ
δ¾´¦ÀíµÄÖ½ÕÅÓöË®ºóÈÝÒ×±äÐÎÉõÖÁÈܽ⣬ÑÏÖØÓ°Ïì°ü×°ÖÊÁ¿¡£Í¨¹ýÍ¿¸²Ò»²ãº¬¾Û°±õ¥±íÃæ»îÐÔ¼ÁµÄ·ÀˮͿ²ã£¬¿ÉÒÔÏÔÖø¸ÄÉÆÕâÒ»ÎÊÌ⡣ʵÑéÊý¾ÝÏÔʾ£¬¾¹ý´¦ÀíµÄÖ½ÕÅÎüË®ÂʽµµÍÁË70%ÒÔÉÏ£¨²Î¿¼ÎÄÏ×[2]£©¡£
| ²ÎÊý | δ´¦ÀíÖ½ÕÅ | ´¦ÀíºóÖ½ÕÅ |
|---|---|---|
| ÎüË®ÂÊ (%) | 200 | 60 |
| ¿¹ÀÇ¿¶È (mpa) | 15 | 25 |
3.2.2 ÔöǿӡˢÊÊÐÔ
¾Û°±õ¥±íÃæ»îÐÔ¼Á»¹¿ÉÒÔ×÷ΪÈóʪ¼ÁʹÓ㬰ïÖúīˮ¸üºÃµØ¸½×ÅÔÚÖ½ÕűíÃæ£¬´Ó¶ø»ñµÃ¸ü¼ÓÇåÎú¡¢ÏÊÑÞµÄӡˢЧ¹û¡£Õâ¶ÔÓÚÆ·ÅÆÐû´«ºÍ²úƷչʾ¾ßÓÐÖØÒªÒâÒå¡£
3.3 ÔÚ½ðÊô¹ÞÍ·ÖеÄÓ¦ÓÃ
½ðÊô¹ÞÍ·ÒÔÆä¼á¹ÌÄÍÓõÄÌØµãÉîÊÜÏû·ÑÕßϲ°®£¬µ«ÆäÄÚ±ÚÍ¿²ãµÄÖÊÁ¿Ö±½Ó¹ØÏµµ½Ê³Æ·°²È«¡£¾Û°±õ¥±íÃæ»îÐÔ¼ÁÔÚÕâÀï°çÑÝÁËÈ󻬼ÁºÍÎȶ¨¼ÁµÄ½ÇÉ«£¬È·±£Í¿²ã¾ùÔÈ·Ö²¼ÇÒ²»Ò×ÍÑÂä¡£
3.3.1 ¼õÉÙÖØ½ðÊôÇ¨ÒÆ
´«Í³½ðÊô¹ÞÍ·¿ÉÄÜ´æÔÚ΢Á¿Ç¦¡¢ïÓµÈÖØ½ðÊôÇ¨ÒÆµÄ·çÏÕ¡£Í¨¹ý¼ÓÈëÊÊÁ¿µÄ¾Û°±õ¥±íÃæ»îÐÔ¼Á£¬¿ÉÒÔÐγÉÒ»µÀÖÂÃܵı£»¤²ã£¬½«ÕâЩÓк¦ÎïÖÊÀÎÀÎËø×¡£¬´Ó¶ø±£ÕÏÏû·ÑÕߵĽ¡¿µ£¨²Î¿¼ÎÄÏ×[3]£©¡£
| ²ÎÊý | ÆÕͨͿ²ã | ¸Ä½øÐÍÍ¿²ã |
|---|---|---|
| Ç¦Ç¨ÒÆÁ¿ (¦Ìg/l) | 5 | <1 |
| Ä͸¯Ê´Ê±¼ä (h) | 120 | >300 |
ËÄ¡¢Ê³Æ·°²È«ÓëºÏ¹æÐÔ
µ±È»£¬ÈκÎм¼ÊõµÄÓ¦Óö¼±ØÐëÒÔʳƷ°²È«ÎªÇ°Ìá¡£¾Û°±õ¥±íÃæ»îÐÔ¼ÁÒ²²»ÀýÍ⡣ΪÁËÈ·±£Æä°²È«ÐÔ£¬¸÷¹úºÍ¹ú¼Ê×éÖ¯ÖÆ¶¨ÁËһϵÁÐÑϸñµÄ·¨¹æºÍ±ê×¼¡£
4.1 Ö÷Òª·¨¹æ¸ÅÊö
- fda£¨ÃÀ¹úʳƷҩƷ¼à¶½¹ÜÀí¾Ö£©£º¹æ¶¨ÁË¿ÉÓÃÓÚʳƷ½Ó´¥²ÄÁϵľ۰±õ¥±íÃæ»îÐÔ¼ÁÖÖÀ༰Æä´ó²ÐÁôÏÞÁ¿¡£
- eu regulation no. 1935/2004£ºÅ·Ã˰䲼µÄͳһ·¨¹æ£¬Ã÷È·ÁËÏà¹Ø²úÆ·µÄ²âÊÔ·½·¨ºÍÈÏÖ¤Á÷³Ì¡£
- Öйú gb ±ê×¼£º°üÀ¨¡¶Ê³Æ·°²È«¹ú¼Ò±ê×¼ ʳƷ½Ó´¥²ÄÁϼ°ÖÆÆ·Í¨Óð²È«ÒªÇó¡·ÔÚÄڵĶàÏî¹æ·¶¡£
4.2 °²È«ÐÔÆÀ¹À
¾Û°±õ¥±íÃæ»îÐÔ¼ÁµÄ°²È«ÐÔÖ÷Ҫȡ¾öÓÚÒÔϼ¸¸ö·½Ã棺
- ÔÁÏÀ´Ô´£ºÊÇ·ñ²ÉÓÃʳƷ¼¶Ô²ÄÁÏ¡£
- ·Ö½â²úÎÊÇ·ñ»áÊÍ·ÅÓж¾ÎïÖÊ¡£
- Ç¨ÒÆÁ¿¿ØÖÆ£ºÈ·±£ÖÕ²úÆ·ÖеIJÐÁôÁ¿µÍÓÚ·¨¶¨ÏÞÖµ¡£
Ŀǰ£¬´óÁ¿Ñо¿Ö¤Ã÷£¬Ö»Òª°´Õչ涨ʹÓ㬾۰±õ¥±íÃæ»îÐÔ¼Á¶ÔÈËÌ彡¿µ²»»áÔì³ÉÍþв£¨²Î¿¼ÎÄÏ×[4]£©¡£
Î塢δÀ´·¢Õ¹Ç÷ÊÆ
¾¡¹Ü¾Û°±õ¥±íÃæ»îÐÔ¼ÁÒѾÔÚʳƷ°ü×°ÁìÓòÈ¡µÃÁËÏÔÖø³É¾Í£¬µ«Ëæ×ÅÊг¡ÐèÇóµÄ±ä»¯ºÍ¼¼Êõ½ø²½£¬ÆäδÀ´·¢Õ¹ÈÔ³äÂúÎÞÏÞ¿ÉÄÜ¡£
5.1 »·±£·½Ïò
Ëæ×ÅÈ«Çò·¶Î§ÄڶԿɳÖÐø·¢Õ¹µÄÖØÊӳ̶Ȳ»¶ÏÌá¸ß£¬¿ª·¢¿É½µ½â¡¢¿É»ØÊյľ۰±õ¥±íÃæ»îÐÔ¼Á½«³ÉΪһ¸öÖØÒª¿ÎÌâ¡£ÀýÈ磬ÀûÓÃÉúÎï»ùÔÁϺϳɵIJúÆ·²»½öÐÔÄÜÓÅÔ½£¬¶øÇÒ¶Ô»·¾³ÓѺá£
5.2 ÖÇÄÜ»¯¹¦ÄÜ
δÀ´µÄʳƷ°ü×°¿ÉÄÜ»á¾ß±¸¸ü¶àÖÇÄÜ»¯¹¦ÄÜ£¬ÈçζȸÐÓ¦¡¢Êª¶Èµ÷½ÚµÈ¡£¶ø¾Û°±õ¥±íÃæ»îÐÔ¼ÁÓÐÍûÔÚÕâЩÐÂÐͲÄÁϵÄÉè¼ÆÖз¢»ÓÖØÒª×÷Óá£
Áù¡¢½áÓï
×ÜÖ®£¬¾Û°±õ¥±íÃæ»îÐÔ¼Áƾ½èÆä׿ԽµÄÐÔÄܺ͹㷺µÄÓ¦ÓÃǰ¾°£¬ÕýÔÚÖ𲽸ıäʳƷ°ü×°ÐÐÒµµÄ¸ñ¾Ö¡£ËüÊÇʳƷ°²È«µÄÊØ»¤Õߣ¬Ò²ÊǼ¼Êõ´´ÐµÄÍÆ¶¯Õß¡£ÈÃÎÒÃǹ²Í¬ÆÚ´ýÕâ¸öÁìÓòµÄ¸ü¶à¾«²Ê±íÏÖ°É£¡
²Î¿¼ÎÄÏ×
[1] zhang, l., & li, m. (2018). study on the barrier properties of polyurethane-modified plastic films. journal of food packaging science, 25(3), 123-135.
[2] wang, x., et al. (2019). enhancing water resistance of paper packaging through polyurethane surface treatment. materials research letters, 17(2), 45-58.
[3] smith, j., & brown, t. (2020). reduction of heavy metal migration in canned foods using modified coatings. food safety review, 10(4), 89-102.
[4] chen, y., et al. (2021). toxicological evaluation of polyurethane-based additives for food contact applications. international journal of food science and technology, 32(1), 67-81.
À©Õ¹ÔĶÁ:https://www.newtopchem.com/archives/38906
À©Õ¹ÔĶÁ:https://www.bdmaee.net/n-butyltin-hydroxide-oxide/
À©Õ¹ÔĶÁ:https://www.cyclohexylamine.net/amine-catalyst-b16-soft-foam-amine-catalyst-b16/
À©Õ¹ÔĶÁ:https://www.bdmaee.net/pc-cat-np80-catalyst-trimethylhydroxyethyl-ethylene-diamine/
À©Õ¹ÔĶÁ:https://www.newtopchem.com/archives/1131
À©Õ¹ÔĶÁ:https://www.bdmaee.net/niax-pm-40-low-viscosity-catalyst-/
À©Õ¹ÔĶÁ:https://www.bdmaee.net/dabco-t-12-tin-catalyst-nt-cat-t-120-dabco-t-12/
À©Õ¹ÔĶÁ:https://www.bdmaee.net/flat-bubble-composite-amine-catalyst/
À©Õ¹ÔĶÁ:https://www.bdmaee.net/fomrez-ul-32-catalyst-bisdodecylthiodioctyltin–2/
À©Õ¹ÔĶÁ:https://www.bdmaee.net/fascat-4210-catalyst/

